Slackcat allows you to send Slack messages from the Linux command line.

Update pi

sudo apt-get update

Install Ruby and other components

sudo apt-get install ruby1.9.1 ruby ruby-dev rubygems

Install Slackcat

sudo gem install slackcat

Use Slackcat.  You will need to generate an API Key from Slacks website.

echo "Hello World" | slackcat -k API-KEY -p --channels=#CHANNEL_NAME

Examples :
Send to Channel

echo "Hello World" | slackcat -k xoxp-94827839414-94819543146-441447827184-h7dt2hg2h8ggs7d24ce638edrw9q8def -p --channels=#General

Send Direct Message

echo "Hello World" | slackcat -k xoxp-94827839414-94819543146-441447827184-h7dt2hg2h8ggs7d24ce638edrw9q8def -p --users=#General